Catalytic combustor for integrated gasification combined cycle power plant

ABSTRACT

A gasification power plant  10  includes a compressor  32  producing a compressed air flow  36,  an air separation unit  22  producing a nitrogen flow  44,  a gasifier  14  producing a primary fuel flow  28  and a secondary fuel source  60  providing a secondary fuel flow  62.  The plant also includes a catalytic combustor  12  combining the nitrogen flow and a combustor portion  38  of the compressed air flow to form a diluted air flow  39  and combining at least one of the primary fuel flow and secondary fuel flow and a mixer portion  78  of the diluted air flow to produce a combustible mixture  80.  A catalytic element  64  of the combustor  12  separately receives the combustible mixture and a backside cooling portion  84  of the diluted air flow and allows the mixture and the heated flow to produce a hot combustion gas  46  provided to a turbine  48.  When fueled with the secondary fuel flow, nitrogen is not combined with the combustor portion.

This invention was made with U.S. Government support through GovernmentContract Number DE-FC26-03NT41891 awarded by the Department of Energy,and, in accordance with the terms set forth in said contract, the U.S.Government may have certain rights in the invention.

FIELD OF THE INVENTION

This invention relates generally to gas turbines, and more particularly,to a catalytic combustor for an integrated gasification combined cycle(IGCC) power plant capable of using multiple fuel types.

BACKGROUND OF THE INVENTION

Catalytic combustion systems are well known in gas turbine applicationsto reduce the creation of pollutants, such as NOx, in the combustionprocess. One catalytic combustion technique known as the rich catalytic,lean burn (RCL) combustion process includes mixing fuel with a firstportion of compressed air to form a rich fuel mixture. The rich fuelmixture is passed over a catalytic surface and partially oxidized, orcombusted, by catalytic action, increasing mixture temperature.Activation of the catalytic surface is first achieved when thetemperature of the rich fuel mixture is elevated to a temperature atwhich the catalytic surface becomes active. Typically, compressionraises the temperature of the air mixed with the fuel to form a richfuel mixture having a temperature sufficiently high to activate thecatalytic surface. After passing over the catalytic surface, theresulting partially oxidized hot rich fuel mixture is then mixed with asecond portion of compressed air in a downstream combustion zone toproduce a heated lean combustion mixture for completing the combustionprocess. Catalytic combustion reactions may produce less NOx and otherpollutants, such as carbon monoxide and hydrocarbons, than pollutantsproduced by homogenous combustion.

U.S. Pat. No. 6,174,159 describes a catalytic combustion method andapparatus for a gas turbine utilizing a backside cooled design. Multiplecooling conduits, such as tubes, are coated on the outside diameter witha catalytic material and are supported in a catalytic reactor. A firstportion of a fuel/air mixture, such as 15% by volume of the fuel/airmixture, is passed over the catalyst coated cooling conduits and iscatalytically combusted, while simultaneously, a second portion of thefuel/air, such as 85% by volume of the fuel/air mixture, enters themultiple cooling conduits and cools the catalyst. The exothermallycatalyzed fluid then exits the catalytic combustion zone and is mixedwith the cooling fluid in a downstream post catalytic combustion zonedefined by a combustor liner, creating a heated, combustible mixture.

Integrated gasification combined cycle (IGCC) power plants are known toproduce synthesis gas, or syngas, from carbon-containing sources such ascoal, Biomass and other sources. The syngas is then used to fuel, usinga conventional diffusion flame process, a combustor of a gas turbineengine connected to a generator for producing electrical power. In IGCCpower plants, the gas turbine is typically required to be capable ofbeing operated on a back-up fuel source, such as natural gas, forexample, during startup and periods when syngas is unavailable.

In a conventional IGCC process, an air separation unit (ASU) is used toprovide oxygen for a gasifier in a separation process that also producescompressed nitrogen as a byproduct. Typically, the nitrogen producedduring the separation process is returned to the combustor. Inconventional diffusion flame combustors used in an IGCC power plant, thesyngas needs to be diluted to reduce a peak syngas flame temperature toachieve acceptable NOx emissions. Dilution is typically achieved withthe injection of ASU produced nitrogen into the syngas provided to thecombustor. In addition, injection of nitrogen into the syngas may beneeded to satisfy the turbine compressor and expander mass flowrequirements.

BRIEF DESCRIPTION OF THE DRAWINGS

The invention will be more apparent from the following description inview of the drawings that show:

FIG. 1 illustrates a schematic diagram of an IGCC plant including animproved catalytic combustor capable of being operated using fuelshaving different BTU ratings.

FIG. 2 shows a cross-sectional view taken along a flow direction of anexemplary embodiment of a catalytic combustor for the IGCC plant of FIG.1.

FIG. 3 shows a cross-sectional view taken along a flow direction ofanother exemplary embodiment of a catalytic combustor for the IGCC plantof FIG. 1.

FIG. 4 shows a cross-sectional view taken along a flow direction ofanother exemplary embodiment of a catalytic combustor for the IGCC plantof FIG. 1.

FIG. 5 shows a table including performance calculations of exemplaryembodiments of the catalytic combustor for the IGCC plant of FIG. 1using a cold gas cleaning IGCC process with syngas reheat to 114°Fahrenheit.

FIG. 6 shows a table including performance calculations of exemplaryembodiments of the catalytic combustor for the IGCC plant of FIG. 1using a cold gas cleaning IGCC process with syngas reheat to 580°Fahrenheit, nitrogen dilution, no humidification, and 0% integration.

FIG. 7 shows a table including performance calculations of exemplaryembodiments of the catalytic combustor for the IGCC plant of FIG. 1using a cold gas cleaning IGCC process with syngas reheat to 580°Fahrenheit, nitrogen dilution, no humidification, and 100% integration.

FIG. 8 shows a table including performance calculations of exemplaryembodiments of the catalytic combustor for the IGCC plant of FIG. 1using a hot gas cleaning IGCC process with syngas heated to 942°Fahrenheit.

DETAILED DESCRIPTION OF THE INVENTION

It is typically desired to start up a gas turbine of an IGCC plant usinga secondary fuel, such as natural gas, and continue fueling the gasturbine with natural gas through at least a portion of a load rampprofile, up to base load operation (such as up to 50% base load). Syngasproduced by the plant is then used as the primary fuel during base loadoperation. Natural gas may also be used as a back up fuel duringgasifier plant outages. While catalytic-type combustors are beingdeveloped to be used in conventional gas turbine power plants to achievereduced pollutant emission levels, the tightly controlled volumetricflows needed to support catalytic combustion has limited theirdevelopment in applications requiring operation with fuels havingdifferent British Thermal Unit (BTU) ratings. Because of thecomparatively large surface area required for catalytic combustion,pressure drop through the combustion system is an important designconsideration. For example, by using a lower BTU fuel, a total flow rateof fuel through a catalytic portion of a catalytic combustor needs to beincreased significantly compared to using a higher BTU fuel, resultingin an unacceptable pressure drop through the catalytic portion of thecatalytic combustor catalyst. Another area of concern when using a lowBTU fuel is the fuel injection system of the combustor. Significantchanges in the fuel flow rates may require a change in the fuelinjection system to obtain an optimized fuel air mixture at the catalystsection of the combustor. Inadequate fuel mixing may result in adecrease in catalytic reaction performance and may result inoverheating. The inventors have innovatively developed a catalyticcombustor for IGCC plants that is capable of operating efficiently usingfuels having different BTU ratings, while keeping pollutant emission,such as NOx emissions, within acceptable levels.

FIG. 1 illustrates a schematic diagram of an IGCC plant 10 including animproved catalytic combustor 12 capable of being operated using fuelshaving different BTU ratings. The plant 10 includes a gasifier 14 fed bya carbonaceous fuel source, such as coal 16, and water 18. The gasifier14 also receives an oxygen flow 20 from an air separation unit (ASU) 22and generates a raw gas flow 24 provided to a gas cleanup system 26. Theraw gas 24 is cleansed in the gas cleanup system 26 using, for example,a cold gas process, a cold gas with syngas reheat process, or hot gascleanup process, to produce clean syngas fuel flow 28 provided to a gasturbine engine 30 as a primary fuel. Valve 29 may be used to control thesyngas fuel flow 28 provided to the gas turbine engine 30. The gasturbine engine 30 includes a compressor 32 for receiving a filteredambient air flow 34 and for producing a compressed air flow 36. Thecompressed air flow 36 may be separated into a combustor portion 38 ofthe compressed air flow 36 for introduction into the catalytic combustor12 and an ASU portion 42 of the compressed air flow for introductioninto the ASU 22. In addition to generating oxygen flow 20 for thegasifier 14, the ASU generates a nitrogen flow 44 for introduction intothe catalytic combustor 12.

The nitrogen flow 44, syngas fuel flow 28, and combustor portion 38 ofthe compressed air flow 36 may be combined and combusted within thecatalytic combustor 12 to produce a hot combustion gas 46. A turbine 48receives the hot combustion gas 46, where it is expanded to extractmechanical shaft power. In one embodiment, a common shaft 50interconnects the turbine 48 with the compressor 12 as well as anelectrical generator (not shown) to provide mechanical power forcompressing the ambient air 14 and for producing electrical power,respectively. An expanded combustion gas 52 may be exhausted directly tothe atmosphere, or it may be routed through additional heat recoverysystems (not shown). In an aspect of the invention, an alternate fuelflow 62, such as natural gas, may be provided to the gas turbine engine30 from fuel source 60. For example, the alternate fuel flow 62 may beprovided to fuel the catalytic combustor 12 of the gas turbine engine 30instead of syngas, such as during start up of the IGCC, and during othertimes when syngas fuel flow 28 is not available. Valve 61 may be used tocontrol the flow of alternate fuel flow 62 provided to the gas turbineengine 30.

The gas turbine engine 30 provides improved operating flexibility forthe IGCC plant as a result of the features of the catalytic combustor 12that are shown more clearly in FIGS. 2-5. FIG. 2 shows a cross-sectionalview of an exemplary embodiment of a catalytic combustor 12 for an IGCCplant 10 capable of combusting at least two types of fuel havingdifferent BTU ratings. For example, a primary fuel, such as syngas maybe used when available, and an alternate fuel flow, such as natural gas,may be used when the primary fuel is unavailable. The catalyticcombustor 12 includes a plurality of catalytic elements 64 spaced apartannularly around a central region 66. The plurality of catalyticelements 64 may be disposed within a cylindrical can 67 spaced radiallyoutward from the elements 64 to form an annular flow path 68 around theelements 64. The annular flow path 68 includes an annular inlet 70 influid communication with a chamber 72 defined by a casing 73 disposedaround a downstream end 75 of the catalytic combustor. The annular flowpath 68 may receive a combustor portion 38 of the compressed air fromthe chamber 72 via the annular inlet 70. A fuel/air mixer 74 combines afuel flow 76, such as at least one of the primary fuel flow andsecondary fuel flow, with a mixer portion 78 of the combustor portion 38to produce a combustible mixture 80. The combustible mixture 80 isprovided to the catalytic element 64 via a combustion mixture inlet 82.A backside cooling portion 84 of the combustor portion 38 may also beprovided to the catalytic element 64 via a backside cooling inlet 86.

Inside the catalytic element 64, the combustible mixture 80 and thebackside cooling portion 84 are separated, for at least a portion of atravel length through the element 64 by a pressure boundary element 88to form a catalytically active flow path 92 and a backside cooling flowpath 94. In an aspect of the invention, the pressure boundary element 88is coated with a catalyst 90 on a side exposed to the combustiblemixture 80. The catalyst 90 may have as an active ingredient of preciousmetals, Group VIII noble metals, base metals, metal oxides, or anycombination thereof. Elements such as zirconium, vanadium, chromium,manganese, copper, platinum, palladium, osmium, iridium, rhodium,cerium, lanthanum, other elements of the lanthanide series, cobalt,nickel, iron, and the like may be used.

In a backside cooling embodiment, an opposite side of the pressureboundary element 88 confines the backside cooling portion 84 for atleast a portion of the travel length. While exposed to the catalyst 90,the combustible mixture 80 is oxidized in an exothermic reaction, andthe catalyst 90 and the pressure boundary element 88 are cooled by theun-reacted backside cooling portion 84, thereby absorbing a portion ofthe heat produced by the exothermic catalytic reaction.

In an aspect of the invention, the pressure boundary element 88 mayinclude a tube for containing a fluid flow. The tube may be coated onits outside diameter surface with a catalyst 90 to be exposed to thecombustible mixture 80 traveling around the exterior of the tube. In abackside cooling arrangement, the backside cooling portion 84 isdirected to travel through the interior of the tube. Alternatively, thetube may be coated on the interior with a catalyst 90 to expose acombustible mixture 80 traveling through the interior of the tube, whilethe backside cooling portion 84 travels around the exterior of the tube.An array of such tubes may be arranged within the catalytic element 64.Other methods may be used to expose the combustion mixture combustiblemixture 80 to the catalyst 90, such as constructing a structure tosuspend the catalyst in the combustible mixture 80, constructing astructure from a catalytic material to suspend in the combustiblemixture 80, or providing pellets coated with a catalyst material exposedto the combustible mixture 80. While the above described catalyticcombustor may be used to efficiently combust a high BTU fuel such asnatural gas, such a design may not meet a low emissions requirementand/or flame stability requirement when using a low BTU fuel, such assyngas available in an IGCC plant, for example, because of differentvolumetric flow requirements of a low BTU fuel.

In an embodiment of the invention, a casing portion 47 of the nitrogenflow 44 produced by the ASU 22 may be mixed with the combustor portion38 of the compressed air flow prior to being mixed with a fuel 76, suchas syngas fuel produced by the gasifier 14. For example, the casingportion 47 of the nitrogen flow 44 may be mixed with the combustorportion 38 prior to being introduced into the annular inlet 70, such asby injecting the casing portion 47 into the chamber 72 via nitrogeninlet 96. The casing portion 47 of the nitrogen flow 44 is allowed tocombine with the combustor portion 38 within the chamber 72 to form adiluted air flow 39 directed into the annular flow path 68 from thechamber 72. The fuel/air mixer 74 receives the mixer portion 78 of thediluted air flow 39 and the fuel flow 76 to produce the combustiblemixture 80 directed into the catalytically active flow path 92. Thecombustible mixture 80 is catalytically combusted to generate apartially combusted mixture 98 discharged from an outlet end 100 of thecatalytic element 64. The backside cooling portion 84 of the diluted airflow 39 is introduced into the backside cooling flow path 94 and isdischarged as a heated flow 102 from outlet end 100. The partiallycombusted mixture 98 and the heated flow 102 combine downstream of thecatalytic element to produce a hot combustion gas 46.

In an aspect of the invention, a nitrogen injection valve 97 may beprovided to selectively control the casing portion 47 of the nitrogenflow 44 entering the chamber 72. Other nitrogen valves 43, controlling abackside portion 45 of the nitrogen flow 44 delivered to the backsidecooling flow path 94 may be closed when providing the casing portion 47to the chamber 72. In a further aspect, the flow paths in the catalyticcombustor 12 may be sized and arranged to accommodate a volumetric flowneeded to support catalytic combustion of a higher BTU fuel, such asnatural gas. During natural gas operation, nitrogen, typicallyunavailable during natural gas operation, is not introduced into thechamber 72. Injection of nitrogen into the combustor portion 38 allowsoperating the catalytic combustor 12 with a lower BTU fuel, such assyngas.

In another embodiment, the backside portion 45 of the nitrogen flow 44may be delivered to the backside cooling flow path 94, for example,instead of being delivered to the chamber 72. Nitrogen flow to thechamber 72 may be limited by closing valve 97 when operating in thismode. The annular flow path 68 may receive a combustor portion 38 of thecompressed air from the chamber 72 via the annular inlet 70. Thefuel/air mixer 74 combines the fuel flow 76, such as syngas, with amixer portion 78 of the combustor portion 38 to produce the combustiblemixture 80 provided, via the combustion mixture inlet 82, to thecatalytically active flow path 92 of the catalytic element 64. Thecombustible mixture 80 is catalytically combusted to produce thepartially combusted mixture 98 discharged from the outlet end 100 of thecatalytic element 64.

The backside cooling portion 84 of the combustor portion 38 may bedirected to combine with the backside portion 45 of the nitrogen flow 44along a backside mixing flow path 104 to produce a backside coolingportion 84 diluted with nitrogen. The backside cooling portion 84,diluted with nitrogen, is provided to the backside cooling flow path 94of the catalytic element 64 via a backside cooling inlet 86 to producethe heated flow 102. The partially combusted mixture 98 and the heatedflow 102 combining downstream of the catalytic element to produce thehot combustion gas 46. In an aspect of the invention, nitrogen valves 43may be provided to selectively control the backside portion 45 of thenitrogen flow 44 entering the backside mixing flow path 104. When thecombustor is operated with an alternate fuel, such as natural gas,valves 43 may be closed so that nitrogen is not allowed to mix with thebackside cooling portion 84. In a further aspect, the flow paths in thecatalytic combustor 12 may be sized and arranged to accommodate avolumetric flow needed to support catalytic combustion of a higher BTUfuel, such as natural gas. During natural gas operation, nitrogen,typically unavailable during natural gas operation, is not introducedinto the backside mixing flow path 104. Injection of nitrogen into thebackside cooling portion 84 allows operating the catalytic combustor 12with a lower BTU fuel, such as syngas.

In yet another embodiment depicted in FIG. 2, the nitrogen flow 44 maybe delivered to the backside cooling flow path 94 and the fuel 76, suchas syngas, may be split so that a portion of the fuel 76 is delivered tothe fuel/air mixer 74 and another portion of the fuel 76 is delivered tothe backside cooling flow path 94. For example, a first fuel portion 77of the fuel 76, and a mixer portion 78 of the combustor portion 38 ofthe compressed air flow 36 are mixed in the fuel/air mixer 74 to producecombustible mixture 80. Upstream of the backside cooling inlet 86, asecond fuel portion 79 of the fuel 76 may be allowed to combine with thenitrogen flow 44 to produce a nitrogen flow 44 comprising afuel/nitrogen mixture, or fuel/nitrogen mixture 108. For example, afuel/nitrogen mixer 106 may be provided upstream of the backside mixingflow path 104 for combining the second fuel portion 79 with the nitrogenflow 44 to produce a fuel/nitrogen mixture 108 that is discharged intothe backside mixing flow path 104. In the mixing flow path 104, thefuel/nitrogen mixture 108 is combined with the backside cooling portion84 prior to entering the backside cooling flow path 94 of the catalyticelement 64. In an aspect of the invention, the second fuel portion 79may be combined with the backside cooling portion 84 prior to enteringthe backside cooling flow path 94 and then combined with the nitrogenflow 44. In another aspect, the second fuel portion 79, the backsidecooling portion 84, and the nitrogen flow 44 may be simultaneouslycombined, for example, before entering the backside cooling flow path94. In yet another aspect, the first fuel portion 77 may comprise about70% to 80% by volume of the fuel 76, and the second fuel portion 79 maycomprise about 20% to 30% by volume of the fuel 76.

FIG. 3 shows a sectional view of another exemplary embodiment of acatalytic combustor 12 for an IGCC plant capable of combusting at leasttwo types of fuel having different BTU ratings. In an embodimentdepicted in FIG. 3, a premixing portion 110 of the combustor portion 38of the compressed air flow 36 may be combined with the fuel 76 upstreamof the fuel/air mixer 74 to produce a premixed fuel/air mixture 112provided to the fuel/air mixer 74. A premix fuel/air mixer 114, forexample, comprising an annular manifold disposed upstream of thefuel/air mixer 74, may be used to distribute the premixing portion 110annularly around the combustor 12 while combining with the fuel 76introduced into the manifold 114. In an aspect of the invention, apremixing conduit 117 may conduct the premixing portion 110 from thechamber 72 to the premix fuel/air mixer 114. A premixing valve 118 maybe provided to selectively control the premix portion 110 flowing intothe premix fuel/air mixer 114. When the combustor 12 is operated withnatural gas, the valve 118 may be closed. The premixing conduit 117 maybe sized to allow sufficient volumetric flow to the catalytic combustor12 to achieve a desired combustor operating condition.

The annular flow path 68 of the catalytic combustor 12 may receive anannular inlet portion 116 of the combustor portion 38 from the chamber72 via the annular inlet 70. The fuel/air mixer 74 combines the premixedfuel/air mixture 112 with the mixer portion 78 of the combustor portion38, via the combustion mixture inlet 82, to produce the combustiblemixture 80 provided to the catalytically active flow path 92 of thecatalytic element 64. The combustible mixture 80 is catalyticallycombusted to produce the partially combusted mixture 98 discharged fromthe outlet end 100 of the catalytic element 64. In an aspect of theinvention, the flow paths of the embodiment of the catalytic combustor12 shown in FIG. 3 may be sized and arranged to accommodate a volumetricflow needed to support catalytic combustion of a higher BTU fuel, suchas natural gas. Premixing of the premixing portion 110 into the fuel 76allows operating the catalytic combustor 12 with a lower BTU fuel, suchas syngas.

In another embodiment of the invention, the flow paths in the catalyticcombustor 12 may be sized and arranged to accommodate a relativelyhigher volumetric flow needed to support catalytic combustion of a lowerBTU fuel, such as syngas, than is conventionally required tocatalytically combust a higher BTU rated fuel, such as natural gas. Forexample, the fuel/air mixer 74, the combustion mixer inlet 82, and athroat 83 of the fuel/air mixer 74 may be sized larger than theseelements would be sized for a catalytic combustor 12 fueled with naturalgas. Consequently, when fueling the catalytic combustor 12 configuredfor such higher volumetric flows with a higher BTU fuel such as naturalgas, a flow modulation element 81, such as valve or a throttle plate,movably mounted in a throat 83 of the fuel/air mixer 74, may be used toselectively control the mixer portion 78 entering the fuel/air mixer 74to optimize the combustor 12 for natural gas operation or syngasoperation. For example, when operating the combustor 12 with naturalgas, the flow modulation element 81 may be positioned to partiallyrestrict the mixer portion 78 entering the fuel/air mixer 74 to achievea desired combustor portion 38 air split between mixer portion and thebackside cooling portion 84. Alternatively, when operating the combustor12 with syngas, the flow modulation element 81 may be positioned so asnot to restrict the mixer portion 78 entering the fuel/air mixer 74 toachieve a desired combustor portion 38 air split between the mixerportion 78 and the backside cooling portion 84.

In an aspect of the invention, the fuel 76, such as the syngas, may besplit prior to entering the premix fuel/air mixer 114 so that a portionof the fuel 76 is delivered to the premix fuel/air mixer 114 and anotherportion of the fuel is delivered to the backside cooling flow path 94.For example, a first fuel portion 77 of the fuel 76 may be provided tothe premix mixer 114 to produce premixed fuel/air mixture 112. Upstreamof the backside cooling inlet 86, a second fuel portion 79 of the fuel76 may be allowed to combine with the with the nitrogen flow 44 toproduce a fuel/nitrogen mixture 108. For example, a fuel/nitrogen mixer106 may be provided upstream of the backside mixing flow path 104 forcombining the second fuel portion 79 with the nitrogen flow 44 toproduce the fuel/nitrogen mixture 108 that is discharged into thebackside mixing flow path 104. In the mixing flow path 104, thefuel/nitrogen mixture 108 is combined with the backside cooling portion84 prior to entering the backside cooling flow path 94 of the catalyticelement 64. In another aspect of the invention, the first fuel portion77 may comprise about 70% to 80% by volume of the fuel 76 and the secondfuel portion 79 may comprise about 20% to 30% by volume of the fuel 76.Nitrogen valves 43 may be provided to selectively control the nitrogenflow 44 entering the backside mixing flow path 104. When the combustor12 is operated with natural gas, the valves 43 may be closed.

In a further aspect of the invention, the premixing conduit 117 maycomprise an eductor 120 disposed upstream of the premix fuel/air mixer114 and receiving an eductor portion 122 of the fuel 76 to pump thepremixing portion 110 flowing through the premixing conduit 117. Apressure of the eductor portion 122 provided to the eductor 120 may becontrolled to achieve a desired volumetric quantity of the premixingportion 110 through the premixing conduit 117.

FIG. 4 shows a sectional view of another exemplary embodiment of acatalytic combustor 12 for an IGCC plant capable of combusting at leasttwo types of fuel having different BTU ratings. In a further aspect ofthe invention depicted in FIG. 4, the catalytic combustor 12 includesannular flow path 68 receiving combustor portion 38 of the compressedair via the annular inlet 70. The fuel/air mixer 74 may combine the fuel76, such as the syngas fuel flow 28, or a first fuel portion 77 of thefuel, with a mixer portion 78 of the combustor portion 38 to produce thecombustible mixture 80 provided, via the combustion mixture inlet 82, tothe catalytically active flow path 92 of the catalytic element 64. Thecombustible mixture 80 is catalytically combusted to produce thepartially combusted mixture 98 discharged from the outlet end 100 of thecatalytic element 64.

Upstream of the backside cooling inlet 86, a second fuel portion 79 ofthe fuel 76 may be allowed to combine with the nitrogen flow 44 toproduce a nitrogen flow 44 comprising a fuel/nitrogen mixture, orfuel/nitrogen mixture 108. For example, a fuel/nitrogen mixer 106 may beprovided upstream of the backside mixing flow path 104 for combining thesecond fuel portion 79 with the nitrogen flow 44 to producefuel/nitrogen mixture 108 that is discharged into the backside mixingflow path 104. In an aspect of the invention, nitrogen valves 43 may beprovided to selectively control the nitrogen flow 44 entering thebackside mixing flow path 104. In the mixing flow path 104, thefuel/nitrogen mixture 108 is combined with the backside cooling portion84 prior to entering the backside cooling flow path 94 of the catalyticelement 64. In an aspect of the invention, the second fuel portion 79may be combined with the backside cooling portion 84 prior to enteringthe backside cooling flow path 94, and then combined with the nitrogenflow 44. In another aspect, the second fuel portion 79, the backsidecooling portion 84, and the nitrogen flow 44 may be simultaneouslycombined, for example, before entering the backside cooling flow path94. The combustible mixture 80 is catalytically combusted to generatepartially combusted mixture 98 discharged from the outlet end 100 of thecatalytic element 64. The backside cooling portion 84 is combined withthe fuel/nitrogen mixture 108 and is introduced into the backsidecooling flow path 94 and is discharged as heated flow 102 from outletend 100.

In a further aspect of the invention, a bypass conduit 124 may beprovided to conduct a bypass portion 126 of the fuel 76 around thecatalytic element 64 and to discharge the bypass portion 126 downstreamof the catalytic element 64 into a post catalytic combustion stage 128.The bypass conduit may discharge the bypass portion 126 into the postcatalytic combustion stage 128 through an opening 130 in a combustionliner 132 defining the post catalytic combustion stage 128. In the postcatalytic combustion stage 128, the bypass portion 126 may be combinedwith the partially combusted mixture 98 and the heated flow 102discharged from the catalytic element 64 to produce a hot combustion gas46.

In yet another aspect, the first fuel portion 77 comprises about 40% to50% by volume of the fuel 76, the second fuel portion 79 comprises about20% to 30% by volume of the fuel 76, and the bypass portion 126comprises about 30% to 40% by volume of the fuel 76. The flow paths ofthe embodiment of the catalytic combustor 12 shown in FIG. 4 may besized and arranged to accommodate a volumetric flow needed to supportcatalytic combustion of a higher BTU fuel, such as natural gas.Bypassing of some of the fuel around the catalytic element 64 allowsoperating the catalytic combustor 12 with a lower BTU fuel, such assyngas.

FIGS. 5-8 show table including performance calculations for theexemplary embodiments of the catalytic combustor for the IGCC plant ofFIG. 1. FIG. 5 shows a table including performance calculations using acold gas cleaning IGCC process with syngas reheat to 114° Fahrenheit.FIG. 6 shows a table including performance calculations using a cold gascleaning IGCC process with syngas reheat to 580° Fahrenheit, nitrogendilution, no humidification, and 0% integration. FIG. 7 shows a tableincluding performance calculations using a cold gas cleaning IGCCprocess with syngas reheat to 580° Fahrenheit, nitrogen dilution, nohumidification, and 100% integration. FIG. 8 shows a table includingperformance calculations using a hot gas cleaning IGCC process withsyngas heated to 5800 Fahrenheit.

In the each of the tables shown in FIGS. 5-8, the first column lists the“Catalytic Combustor Configuration,” such as a catalytic combustorconfigured for combining nitrogen with casing air as describedpreviously. The “Fuel Type” column lists the type of fuel used for therespective catalytic combustor configuration, such as syngas. The “FuelTo” column lists the element(s) of the catalytic combustor that is (are)being fueled for each respective catalytic combustor configuration. The“Nitrogen To” column lists the element(s) of the catalytic combustorthat is (are) being provided nitrogen for each respective catalyticcombustor configuration using syngas as a fuel. In the case of naturalgas fueling, nitrogen may not be provided even though the respectivecombustor configuration may be capable of receiving nitrogen. The “AirSplit” column lists the air split between the catalytically active flowpath and the backside cooling flow path for each respective catalyticcombustor configuration. The “Max Tube Temperature” column lists themaximum tube temperatures of the catalytic tubes for each respectivecatalytic combustor configuration. The “Product Gas Temperature” columnlists the hot combustion gas temperature tubes for each respectivecatalytic combustor configuration. The “Pressure Drop” column lists thepressure drop from the inlet of the catalytic combustor to the outlet ofthe catalytic combustor for each respective catalytic combustorconfiguration.

While the preferred embodiments of the present invention have been shownand described herein, it will be obvious that such embodiments areprovided by way of example only. Numerous variations, changes andsubstitutions will occur to those of skill in the art without departingfrom the invention herein. Accordingly, it is intended that theinvention be limited only by the spirit and scope of the appendedclaims.

1. A gasification power plant comprising: a compressor receiving anambient air flow and producing a compressed air flow; an air separationunit receiving an air separation unit portion of the compressed airflow, and producing a nitrogen flow and an oxygen flow; a gasifierreceiving the oxygen flow, carbonaceous fuel, and water, and producing aprimary fuel flow; a fuel supply providing a secondary fuel flow; acatalytic combustor comprising a diluent mixing flow path combining thenitrogen flow and a combustor portion of the compressed air flow to forma diluted air flow, a fuel/air mixer combining at least one of theprimary fuel flow and secondary fuel flow with a mixer portion of thediluted air flow to produce a combustible mixture; a catalytic elementhaving a catalytically active flow path receiving the combustiblemixture and producing a partially combusted mixture and a backsidecooling flow path receiving a backside cooling portion of the dilutedair flow and producing a heated flow, the partially combusted mixtureand the heated flow combining downstream of the catalytic element toproduce a hot combustion gas; and a turbine receiving the hot combustiongas and expanding the hot combustion gas to extract mechanical shaftpower.
 2. The gasification power plant of claim 1, wherein the diluentmixing flow path is defined by a casing disposed around a downstream endof the catalytic combustor comprising a nitrogen inlet receiving thenitrogen flow.
 3. The gasification power plant of claim 1, wherein theprimary fuel flow comprises syngas and the secondary fuel flow comprisesnatural gas.
 4. A gasification power plant comprising: a compressorreceiving an ambient air flow and producing a compressed air flow; anair separation unit receiving an air separation unit portion of thecompressed air flow, and producing a nitrogen flow and an oxygen flow; agasifier receiving the oxygen flow, carbonaceous fuel, and water, andproducing a primary fuel flow; a fuel supply providing a secondary fuelflow; a catalytic combustor comprising a flow path receiving a combustorportion of the compressed air flow, a fuel/air mixer combining at leastone of the primary fuel flow and secondary fuel flow and a mixer portionof the combustor portion to produce a combustible mixture; a backsidemixing flow path combining the nitrogen flow and a backside coolingportion of the combustor portion of the compressed air flow to produce adiluted air flow, a catalytic element having a catalytically active flowpath receiving the combustible mixture and producing a partiallycombusted mixture and a backside cooling flow path receiving the dilutedair flow and producing a heated flow, the partially combusted mixtureand the heated flow combining downstream of the catalytic element toproduce a hot combustion gas; and a turbine receiving the hot combustiongas and expanding the hot combustion gas to extract mechanical shaftpower.
 5. The gasification power plant of claim 4, wherein the primaryfuel flow comprises syngas and the secondary fuel flow comprises naturalgas.
 6. A gasification power plant comprising: a compressor receiving anambient air flow and producing a compressed air flow; an air separationunit receiving an air separation unit portion of the compressed airflow, and producing a nitrogen flow and an oxygen flow; a gasifierreceiving the oxygen flow, carbonaceous fuel, and water, and producing aprimary fuel flow; a fuel supply providing a secondary fuel flow; acatalytic combustor comprising a flow path receiving a combustor portionof the compressed air flow, a fuel/air mixer combining a first fuelportion of at least one of the primary fuel flow and secondary fuel flowand a mixer portion of the combustor portion to produce a combustiblemixture; a fuel/nitrogen mixer combining a second fuel portion of atleast one of the primary fuel flow and secondary fuel flow and thenitrogen flow to produce a fuel/nitrogen mixture, a backside mixing flowpath combining the fuel/nitrogen mixture and a backside cooling portionof the combustor portion to produce a fuel/nitrogen/air mixture, acatalytic element having a catalytically active flow path receiving thecombustible mixture and producing a partially combusted mixture and abackside cooling flow path receiving the fuel/nitrogen/air mixture andproducing a heated mixture, the partially combusted mixture and theheated mixture combining downstream of the catalytic element to producea hot combustion gas; and a turbine receiving the hot combustion gas andexpanding the hot combustion gas to extract mechanical shaft power. 7.The gasification power plant of claim 6, wherein: the first fuel portioncomprises about 70% to 80% by volume of at least one of the primary fuelflow and secondary fuel flow; and the second fuel portion comprisesabout 20% to 30% by volume of at least one of the primary fuel flow andsecondary fuel flow.
 8. The gasification power plant of claim 6, whereinthe primary fuel flow comprises syngas and the secondary fuel flowcomprises natural gas.
 9. A gasification power plant comprising: acompressor receiving an ambient air flow and producing a compressed airflow; an air separation unit receiving an air separation unit portion ofthe compressed air flow, and producing a nitrogen flow and an oxygenflow; a gasifier receiving the oxygen flow, carbonaceous fuel, andwater, and producing a primary fuel flow; a fuel supply providing asecondary fuel flow; a catalytic combustor comprising a first fuel/airmixer receiving a first combustor portion of the compressed air flow andcombining a first fuel portion of at least one of the primary fuel flowand secondary fuel flow and the first combustor portion to produce afirst combustible mixture; an air flow path receiving a second combustorportion of the compressed air flow, a second fuel/air mixer combiningthe first combustible mixture and a mixer portion of the secondcombustor portion to produce a second combustible mixture; afuel/nitrogen mixer combining a second fuel portion of at least one ofthe primary fuel flow and secondary fuel flow and the nitrogen flow toproduce a fuel/nitrogen mixture, a backside mixing flow path combiningthe fuel/nitrogen mixture and a backside cooling portion of the secondcombustor portion to produce a fuel/nitrogen/air mixture, a catalyticelement having a catalytically active flow path receiving the secondcombustible mixture and producing a partially combusted mixture and abackside cooling flow path receiving the fuel/nitrogen/air mixture andproducing a heated mixture, the partially combusted mixture and theheated mixture combining downstream of the catalytic element to producea hot combustion gas; and a turbine receiving the hot combustion gas andexpanding the hot combustion gas to extract mechanical shaft power. 10.The gasification power plant of claim 9, further comprising: a casingdisposed around a downstream end of the catalytic combustor receivingthe combustor portion; and a bypass conduit conducting the firstcombustor portion from the casing to the first fuel/air mixer.
 11. Thegasification power plant of claim 10, further comprising an eductordisposed in the bypass conduit upstream of the first fuel/air mixer andreceiving a third fuel portion of at least one of the primary fuel andthe secondary fuel to pump the first combustor portion flowing throughthe bypass conduit.
 12. The gasification power plant of claim 9,wherein: the first fuel portion comprises about 70% to 80% by volume ofat least one of the primary fuel flow and secondary fuel flow; and thesecond fuel portion comprises about 20% to 30% by volume of at least oneof the primary fuel flow and secondary fuel flow.
 13. The gasificationpower plant of claim 9, wherein the primary fuel flow comprises syngasand the secondary fuel flow comprises natural gas.
 14. A gasificationpower plant comprising: a compressor receiving an ambient air flow andproducing a compressed air flow; an air separation unit receiving an airseparation unit portion of the compressed air flow, and producing anitrogen flow and an oxygen flow; a gasifier receiving the oxygen flow,carbonaceous fuel, and water, and producing a primary fuel flow; a fuelsupply providing a secondary fuel flow; a catalytic combustor comprisinga flow path receiving a first portion of a combustor portion of thecompressed air flow, a first fuel/air mixer combining at least one ofthe primary fuel flow and secondary fuel flow and a mixer portion of thefirst combustor portion to produce a combustible mixture, the firstfuel/air mixer comprising a throttle selectively controlling the firstfuel/air mixer portion entering the mixer; a catalytic element having acatalytically active flow path receiving the combustible mixture andproducing a partially combusted mixture and a backside cooling flow pathreceiving a backside cooling portion of the first portion of thecombustor portion and producing a heated flow, the partially combustedmixture and the heated flow combining downstream of the catalyticelement to produce a hot combustion gas; and a turbine receiving the hotcombustion gas and expanding the hot combustion gas to extractmechanical shaft power.
 15. The gasification power plant of claim 14,further comprising a second fuel/air mixer receiving a second combustorportion of the compressed air flow and combining at least one of theprimary fuel flow and secondary fuel flow and the second combustorportion prior to entering the second fuel/air mixer.
 16. Thegasification power plant of claim 15, further comprising: a casingdisposed around a downstream end of the catalytic combustor receivingthe combustor portion of the compressed air flow; and a bypass conduitconducting the second portion of the combustor portion from the casingto the second fuel/air mixer.
 17. The gasification power plant of claim14, wherein the primary fuel flow comprises syngas and the secondaryfuel flow comprises natural gas.
 18. A gasification power plantcomprising: a compressor receiving an ambient air flow and producing acompressed air flow; an air separation unit receiving an air separationunit portion of the compressed air flow, and producing a nitrogen flowand an oxygen flow; a gasifier receiving the oxygen flow, carbonaceousfuel, and water, and producing a primary fuel flow; a fuel supplyproviding a secondary fuel flow; a catalytic combustor comprising a flowpath receiving a combustor portion of the compressed air flow, afuel/air mixer combining a first fuel portion of at least one of theprimary fuel flow and secondary fuel flow and a mixer portion of thecombustor portion to produce a combustible mixture; a fuel/nitrogenmixer combining a second fuel portion of at least one of the primaryfuel flow and secondary fuel flow and the nitrogen flow to produce afuel/nitrogen mixture, a backside mixing flow path combining thefuel/nitrogen mixture and a backside cooling portion of the combustorportion to produce a fuel/nitrogen/air mixture, a catalytic elementhaving a catalytically active flow path receiving the combustiblemixture and producing a partially combusted mixture and a backsidecooling flow path receiving the fuel/nitrogen/air mixture and producinga heated combustible mixture, a bypass conduit receiving a third fuelportion of at least one of the primary fuel flow and secondary fuel flowand discharging the third fuel portion downstream of the catalyticelement to combine with the partially combusted mixture and the heatedcombustible mixture discharged from the catalytic element to produce ahot combustion gas; and a turbine receiving the hot combustion gas andexpanding the hot combustion gas to extract mechanical shaft power. 19.The catalytic combustor of claim 18, wherein the first fuel portioncomprises about 40% to 50% by volume of at least one of the primary fuelflow and secondary fuel flow.
 20. The catalytic combustor of claim 18,wherein the second fuel portion comprises about 20% to 30% by volume ofat least one of the primary fuel flow and secondary fuel flow.
 21. Thecatalytic combustor of claim 18, wherein the third fuel portioncomprises about 30% to 40% by volume of at least one of the primary fuelflow and secondary fuel flow.
 22. The gasification power plant of claim18, wherein the primary fuel flow comprises syngas and the secondaryfuel flow comprises natural gas.
 23. A gasification power plantcomprising: means for receiving an ambient air flow and producing acompressed air flow; means for receiving an air separation unit portionof the compressed air flow, and producing a nitrogen flow and an oxygenflow; means for receiving the oxygen flow, carbonaceous fuel, and water,and producing a primary fuel flow; means for providing a secondary fuelflow; means for catalytically combusting a fuel/air mixture comprisingan air mixing flow path combining the nitrogen flow and a combustorportion of the compressed air flow to form a diluted air flow, afuel/air mixer combining at least one of the primary fuel flow andsecondary fuel flow and a mixer portion of the diluted air flow toproduce a combustible mixture; a catalytic element having acatalytically active flow path receiving the combustible mixture andproducing a partially combusted mixture and a backside cooling flow pathreceiving a backside cooling portion of the diluted air flow andproducing a heated flow, the partially combusted mixture and the heatedflow combining downstream of the catalytic element to produce a hotcombustion gas; and means for receiving the hot combustion gas andexpanding the hot combustion gas to extract mechanical shaft power.